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We investigated the optical phonon excitations of laterally aligned nanorod arrays by resonant Raman scattering. We observed a strong suppression of the surface-optical phonon modes in the closely packed aligned arrays and a small asymmetry in the longitudinal-optical phonon peak with respect to the rod alignment orientation. These observations can be explained by the spatial distribution of the potential of the different phonon modes derived from the first principles calculations.
American Chemical Society
Publication date: 
14 Feb 2007

Concetta Nobile, Vladimir A Fonoberov, Stefan Kudera, Antonio Della Torre, Antonio Ruffino, Gerwin Chilla, Tobias Kipp, Detlef Heitmann, Liberato Manna, Roberto Cingolani, Alexander A Balandin, Roman Krahne

Biblio References: 
Volume: 7 Issue: 2 Pages: 476-479
Nano letters