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In the realm of semiconductor nanomaterials, a crystal lattice heavily doped with cation/anion vacancies or ionized atomic impurities is considered to be a general prerequisite to accommodating excess free carriers that can support localized surface plasmon resonance (LSPR). Here, we demonstrate a surfactant-assisted nonaqueous route to anisotropic copper sulfide nanocrystals, selectively trapped in the covellite phase, which can exhibit intense, size-tunable LSPR at near-infrared wavelengths despite their stoichiometric, undoped structure. Experimental extinction spectra are satisfactorily reproduced by theoretical calculations performed by the discrete dipole approximation method within the framework of the Drude–Sommerfeld model. The LSPR response of the nanocrystals and its geometry dependence are interpreted as arising from the inherent metallic-like character of covellite, allowed by a significant …
American Chemical Society
Publication date: 
27 Aug 2013

Yi Xie, Luigi Carbone, Concetta Nobile, Vincenzo Grillo, Stefania D’Agostino, Fabio Della Sala, Cinzia Giannini, Davide Altamura, Christian Oelsner, Carola Kryschi, P Davide Cozzoli

Biblio References: 
Volume: 7 Issue: 8 Pages: 7352-7369
ACS nano